Is it possible to get off at a stop that is not in the schedule?

Boarding and alighting at stops not specified by the route are prohibited.

List of permitted stops on the Kyiv – Kharkiv route: Kyiv, Boryspil, Berezan, Yahotyn, Oleksiivka, Pyriatyn, Vily, Mhar, Pokrovska Bahachka, Khorol, Krasnohorivka, Podil, Reshetylivka, Poltava, Chutove, Snizhkiv, Valky, Pisochyn, Kharkiv.